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・ Methyl diethanolamine
・ Methyl dihydrojasmonate
・ Methyl ethyl ketone peroxide
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Methyl isocyanide
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Methyl isocyanide : ウィキペディア英語版
Methyl isocyanide

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Methyl isocyanide or isocyanomethane is an organic compound and a member of the isocyanide family. This colorless liquid is isomeric to methyl cyanide (acetonitrile), but its reactivity is very different. Methyl isocyanide is mainly used for making 5-membered heterocyclic rings. The C-N distance in methyl isocyanides is very short, 1.158 Å as is characteristic of isocyanides.
〔Myer Kessler, Harold Ring, Ralph Trambarulo, Walter Gordy "Microwave Spectra and Molecular Structures of Methyl Cyanide and Methyl Isocyanide" Phys. Rev. 1950, vol. 79, 54–56. 〕
==Preparation and uses==
Methyl isocyanide was first prepared Gautier by reaction of silver cyanide with methyl iodide. The common method for preparing methyl isocyanides is the dehydration of N-methylformamide.
Methyl isocyanide is useful for the preparation of diverse heterocycles. It is also a ligand in organometallic chemistry.

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